156 Asbestos that is immersed or fixed in a natural or artificial binder material, such as cement, plastic, asphalt, resins or mineral ore, or contained in manufactured products is not subject to the requirements of this subchapter. Any glass inner packaging showing evidence of leakage, distortion or other defect under this test must not be transported under the terms of this special provision; b. When transported by vessel, flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. Transportation by vessel in IBCs is prohibited. These special provisions are in addition to the standard packaging requirements. The material must be packaged so that the percentage of diluent does not fall below that stated in the approval at any time during transportation. PDF 173.242 49 CFR Ch. I (10-1-04 Edition) - GovInfo Lithium ion cells and batteries at a state of charge greater than 30 percent of their rated capacity may only be transported under conditions approved by the Associate Administrator in accordance with the requirements in 49 CFR part 107, subpart H. Guidance and methodology for determining the rated capacity can be found in sub-section 38.3.2.3 of the UN Manual of Tests and Criteria (IBR, see 171.7 of this subchapter). US Department of Transportation (DOT) Pipeline Hazardous Materials Safety N20 A 5M1 multi-wall paper bag is authorized if transported in a closed transport vehicle. e. When offered for transport in an ammonia dispenser, the receptacles shall be connected to the dispenser in such a way that the assembly is guaranteed to have the same strength as a single receptacle. The material is also be subject to operational controls which include not exceeding a temperature of 55C (130F) at the time it is offered or during transportation, not exceeding a transportation time of 24 hours, and drivers transporting spent bleaching earth must be trained in the properties and hazards of the spent bleaching earth. (5) A code containing the letter N refers to a special provision which applies only to non-bulk packaging requirements. A189 Except where the defining criteria of another class or division are met, concentrations of formaldehyde solution: a. Column 1 uses six symbols to identify hazardous materials with special shipping conditions such as restrictions for air, domestic, international, or water vessel transport. For a battery whose voltage (electrical potential) exceeds 9 volts -, (1) When contained in a device, the device must be packaged in a manner that prevents unintentional activation or must have an independent means of preventing unintentional activation (e.g., packaging restricts access to activation switch, switch caps or locks, recessed switches, trigger locks, temperature sensitive circuit breakers, etc. Unlined tanks must be passivated before being placed in service. Where different hazardous materials in limited quantities are packed together in the same outer packaging, when a gross mass is indicated Column 4 of 173.27 Table 3, the net quantity of each hazardous material must be shown in addition to the gross mass of the completed package. When a plus sign is assigned to mix- TP47 The 2.5 year internal examination may be waived or substituted by other test methods or inspection procedures specified by the competent authority or its authorized body, provided that the portable tank is dedicated to the transport of the organometallic substances to which this tank special provision is assigned. Packaging Authorizations (Column 8) The purpose of this article is to explain the meaning of the coding system for the Special Provisions of column 7 in order to facilitate your review and understanding of them and how they may apply to your shipment of a hazardous material. (TOY CAPS) - HANDLE CAREFULLY OR TOY CAPS - HANDLE CAREFULLY; and. On the basis of the results of suitable burning rate tests, and taking into account the standard tests in the UN Manual of Tests and Criteria, Part III, subsection 33.2.1 (IBR, see 171.7 of this subchapter), nitrocellulose membrane filters in the form in which they are to be transported that do not meet the criteria for a Division 4.1 material are not subject to the requirements of this subchapter. IBCs are only authorized if approved by the Associate Administrator. (vi) Except when an organic peroxide is authorized under 173.225(g), if a hazardous material is not assigned a portable tank T Code, the hazardous material may not be transported in a portable tank unless approved by the Associate Administrator. 134 This entry applies only to vehicles powered by wet batteries, sodium batteries, lithium metal batteries or lithium ion batteries, and equipment powered by wet batteries or sodium batteries that are transported with these batteries installed. However, the design stress limits may not exceed 25 percent of the stress for 0 temper at the maximum design temperature of the cargo tank, as specified in the Aluminum Association's Aluminum Standards and Data (IBR, see 171.7 of this subchapter). 41 This material at the Packing Group II hazard criteria level may be transported in Large Packagings. For continued use of approvals dated prior to January 1, 2012, see 173.308(b)(5). 107 The classification of the substance is expected to vary especially with the particle size and packaging but the border lines have not been experimentally determined; appropriate classifications should be verified following the test procedures in 173.57 and 173.58 of this subchapter. Decomposition can be initiated by heat, moisture or by impurities (e.g., powdered metals (iron, manganese, cobalt, magnesium)). When no IB code is assigned in the 172.101 Table for a specific proper shipping name, or in 173.185 or 173.225(e) Organic Peroxide Table for Type F organic peroxides, use of an IBC or Large Packaging for the material may be authorized when approved by the Associate Administrator. Lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a temperature of 23 C 2 C, exhibit a solubility of 5% or less are not subject to the requirements of this subchapter unless they meet criteria as another hazard class or division. The temperature of the material at the time it is offered for transport and during transportation may not exceed 55 C (130 F). Column 7 of the HMT specifies codes for special provisions applicable to packaging, packaging requirements, certification, and marking or labeling for a hazardous material. Air must be eliminated from the vapor space by nitrogen or other means. Codes in Column 7 may be numbers, or a combination of letters and numbers. B133 Hydrochloric acid concentration not exceeding 38%, in Packing Group II, is authorized to be packaged in UN31H1 or UN31HH1 intermediate bulk containers when loaded in accordance with the requirements of 173.35(h) of this subchapter. The coal tar pitch compound must be in a solid mass during transportation. N78 Packages consisting of inner glass, earthenware, or polyethylene or other nonfragile plastic bottles or jars not over 0.5 kg (1.1 pounds) capacity each, or metal cans not over five pounds capacity each, packed in outer wooden boxes, barrels or kegs, or fiberboard boxes are authorized and need not conform to the requirements of part 178 of this subchapter. A212 UN 2031, Nitric acid, other than red fuming, with more than 20% and less than 65% nitric acid intended for use in sterilization devices only, may be transported on passenger aircraft irrespective of the indication of forbidden in columns (9A) of the 172.101 table provided that: a. A series of notes is used throughout TABLE 1 and TABLE 2 to provide additional information concerning certain hazardous substances. Lead-free Solder Figure 3: Engineer soldering a microcircuit Note, Tin here is the primary metal. The capacity of each drum must not exceed 220 L (58 gallons). Sealed packets and articles containing less than 10 mL of a Class 3 liquid in Packing Group II or III absorbed onto a solid material are not subject to this subchapter provided there is no free liquid in the packet or article. This contact form is only for website help or website suggestions. For single packagings, each packaging must correspond to a design type that has passed a leakproofness test at the Packing Group II level. TP4 The maximum degree of filling for portable tanks must not exceed 90%. Batteries must be securely cushioned and packed to prevent shifting which could loosen terminal caps or reorient the terminals to produce short circuits. 370 This entry also applies to ammonium nitrate with not more than 0.2% combustible substances, including any organic substance calculated as carbon, to the exclusion of any added substance, that gives a positive result when tested in accordance with Test Series 2 of the UN Manual of Tests and Criteria, Part I (IBR; see 171.7 of this subchapter). 113 The sample must be given a tentative approval by an agency or laboratory in accordance with 173.56 of this subchapter. A5 Solids having an inhalation toxicity of Packing Group I are not permitted on passenger aircraft and may not exceed a maximum net quantity per package of 15 kg (33 pounds) on cargo aircraft. When a consignment is undeliverable, the consignment shall be placed in a safe location and the appropriate competent authority shall be informed as soon as possible and a request made for instructions on further action. TP9 A hazardous material assigned to special provision TP9 in Column (7) of the 172.101 Table may only be transported in a portable tank if approved by the Associate Administrator. Testing must be conducted on at least three packages as prepared for transport. In addition, the material also must be covered with an inert gas or the container must be filled with water to the tank's capacity. a. Metal: 11A, 11B, 11N, 21A, 21B and 21N, b. 2 Except when authorized under Special Provision 41. 430 This entry shall only be used for solid medical waste of Category A transported for disposal. Examples of such vehicles are cars, motorcycles, trucks, locomotives, scooters, three- and four-wheeled vehicles or motorcycles, lawn tractors, self-propelled farming and construction equipment, boats, and aircraft. (i) Tests must be performed on each type and size of bottle, for each manufacturing location. TP22 Lubricants for portable tank fittings (for example, gaskets, shut-off valves, flanges) must be oxygen compatible. individual packaging placed or stacked and secured by strapping, shrink or stretch-wrapping or other suitable means to a pallet). not more than 0.1 mL/hour per 30 mL inner packaging at 20 C (68 F) produced from gradual decomposition. 172.101 Purpose and use of hazardous materials table - eCFR Additionally, each cylinder must be visually inspected in accordance with CGA pamphlet, CGA C-6 (incorporated by reference, see 171.7). 114 Jet perforating guns, charged, oil well, without detonator may be reclassed to Division 1.4 Compatibility Group D (1.4D) if the following conditions are met: a. For transportation by passenger-carrying aircraft, the net mass of lighter refills may not exceed 1 kg per package, and, for cargo-only aircraft, the net mass of lighter refills may not exceed 15 kg per package. The receptacle must contain no hazardous materials other than the liquid nitrogen which must be fully absorbed in a porous material in the receptacle. Refrigerated liquefied gases that are authorized to be transported in portable tanks are specified in tank instruction T75. 3090 or 3091, as appropriate. 15 This entry applies to Chemical kits and First aid kits containing one or more compatible items of hazardous materials in boxes, cases, etc. 19 For domestic transportation only, the identification number UN1075 may be used in place of the identification number specified in column (4) of the 172.101 table. 46 This material must be packed in accordance with packing method OP6 (see 173.225 of this subchapter). 35 Antimony sulphides and oxides which do not contain more than 0.5 percent of arsenic calculated on the total mass do not meet the definition of Division 6.1. B54 Open-top, sift-proof rail cars are also authorized. Company Name: Artisan EHS Consulting, LLC. The vacant space (outage) may be charged with a nonflammable nonliquefied compressed gas if the pressure in the cylinder or sphere at 55 C (130 F) does not exceed 125 percent of the marked service pressure. a. Mixtures of one or more organic lead mixtures (such as tetraethyl lead, triethylmethyl lead, diethyldimethyl lead, ethyltrimethyl lead, and tetramethyl lead) with one or more halogen compounds (such as ethylene dibromide and ethylene dichloride), hydrocarbon solvents or other equally efficient stabilizers; or. N75 Packages consisting of tightly closed inner packagings of glass, earthenware or metal, securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, capacity not over 2.5 kg (5.5 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter. 349 Mixtures of hypochlorite with an ammonium salt are forbidden for transport. 50 Cases, cartridge, empty with primer which are made of metallic or plastic casings and meeting the classification criteria of Division 1.4 are not regulated for domestic transportation. switch to drafting.ecfr.gov. (3) A code containing the letter B refers to a special provision that applies only to bulk packaging requirements. c. Completed neutron radiation detection systems containing detectors meeting the conditions of paragraph a of this special provision must be transported as follows: (1) The detectors must be contained in a strong sealed outer casing; (2) The casing must contain include sufficient absorbent or adsorbent material to absorb or adsorb the entire gas contents; (3) The completed system must be packed in strong outer packagings capable of withstanding a 1.8 meter (5.9 feet) drop test without leakage unless a system's outer casing affords equivalent protection. The suitability for transport in tanks must be demonstrated using test 8(d) in Test Series 8 (see UN Manual of Tests and Criteria, Part 1, Sub-section 18.7) (IBR, see 171.7 of this subchapter) or an alternative means approved by the Associate Administrator. A Shipper of a hazardous material is responsible for its classification and packaging prior to offering it for shipment to a Carrier. B25 Packagings must be made from monel or nickel or monel-lined or nickel-lined steel. The consignor shall be in possession of a copy of each applicable certificate when packages include fissile material excepted by competent authority approval. Nitrocellulose membrane filters covered by this entry, each with a mass not exceeding 0.5 g, are not subject to the requirements of this subchapter when contained individually in an article or a sealed packet. When chemical stabilization is employed, the person offering the material for transport shall ensure that the level of stabilization is sufficient to prevent the material as packaged from dangerous polymerization at 50 C (122 F). N95 UN1075, Liquefied petroleum gas and UN1978, Propane authorized for transport in DOT 4BA240 cylinders is not subject to the UN identification number and proper shipping name marking or the label requirements of this part subject to the following conditions: a. Packagings may include a vent to permit the slow escape of gas (i.e. For all modes of transportation, a written report submitted, retained, and updated in accordance with 171.16 is required if a fire, violent rupture, explosion or dangerous evolution of heat occurs as a direct result of a dry battery or battery-powered device. 121 This substance, when containing less alcohol, water or phlegmatizer than specified, may not be transported unless approved by the Associate Administrator. 440 When this material is transported by tank car, the offeror must ensure each tank car is remotely monitored for pressure and location. Subpart BTable of Hazardous Materials and Special Provisions 172.101 Purpose and use of haz-ardous materials table. TP28 A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in 178.275 of this subchapter, where the test pressure is 1.5 times the MAWP. The manufacturer must provide such information to a representative of the Department upon request. These provisions apply only to transportation by rail. W9 When offered for transportation by water, the following Specification packagings are not authorized unless approved by the Associate Administrator: woven plastic bags, plastic film bags, textile bags, paper bags, IBCs and bulk packagings. PDF 171.26 49 CFR Ch. I (10-1-11 Edition) - GovInfo Regulation Y 138 This entry applies to lead compounds which, when mixed in a ratio of 1:1,000 with 0.07 M (Molar concentration) hydrochloric acid and stirred for one hour at a temperature of 23 C 2 C, exhibit a solubility of more than 5%. The organic peroxide must be type D, E, or F, not requiring temperature control. 38 If this material shows a violent effect in laboratory tests involving heating under confinement, the labeling requirements of Special Provision 53 apply, and the material must be packaged in accordance with packing method OP6 in 173.225 of this subchapter. Data collection and handling. f. Chemicals under pressure containing components forbidden for transport on both passenger and cargo aircraft in Columns (9A) and (9B) of the 172.101 Hazardous Materials Table must not be transported by air. If one of the components, which can be a pure substance or a mixture, is classed as flammable, the chemical under pressure must be classed as flammable in Division 2.1. See 173.306(h) of this subchapter. With less than 10 percent formaldehyde, are not subject to this subchapter. B59 Water-tight, sift-proof, closed-top, metal-covered hopper cars are also authorized provided that the lading is covered with a nitrogen blanket. (3) Damage to terminals. a. Where the quantity of hazardous materials contained as an integral element in machinery or apparatus exceeds the limits permitted by 173.222(c)(2), and the hazardous materials meet the provisions of 173.222(c), the machinery or apparatus may be transported by aircraft only with the prior approval of the Associate Administrator. The tank car specification may be marked to indicate a test pressure of 13.79 Bar (200 psig). B30 MC 312, MC 330, MC 331 and DOT 412 cargo tanks and DOT 51 portable tanks must be made of stainless steel, except that steel other than stainless steel may be used in accordance with the provisions of 173.24b(b) of this subchapter. 115 Boosters with detonator, detonator assemblies and boosters with detonators in which the total explosive charge per unit does not exceed 25 g, and which will not mass detonate and undergo only limited propagation in the shipping package may be assigned to 1.4B classification code. 168 For lighters containing a Division 2.1 gas (see 171.8 of this subchapter), representative samples of each new lighter design must be examined and successfully tested as specified in 173.308(b)(3). Portable tanks must be hydraulically tested and internally inspected at intervals not exceeding 2.5 years. (1) Numeric provisions. Nickel-metal hydride button cells or nickel-metal hydride cells or batteries packed with or contained in battery-powered devices transported by vessel are not subject to the requirements of this special provision. Such packages must be transported on cargo aircraft only. The cylinder must be transported in a closed motor vehicle displaying FLAMMABLE GAS placards in accordance with subpart F of part 172 of this subchapter. PDF 4756 Federal Register /Vol. 88, No. 16/Wednesday, January 25, 2023 N90 Metal packagings are not authorized. Size of marking on bulk package must conform to 172.302(b) of this subchapter. 136 This entry applies only to articles, machinery, and apparatus containing hazardous materials as an integral element of the article, machinery, or apparatus. 3 This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone C (see 173.116(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter. Interior heating coils are not authorized. - Other Regulations Relating to Transportation, - Pipeline and Hazardous Materials Safety Administration, Department of Transportation, - Hazardous Materials Table, Special Provisions, Hazardous Materials Communications, Emergency Response Information, Training Requirements, and Security Plans, - Table of Hazardous Materials and Special Provisions, https://www.ecfr.gov/current/title-49/subtitle-B/chapter-I/subchapter-C/part-172/subpart-B/section-172.102.
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